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Creators/Authors contains: "He, Wen-Ji"

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  1. ; ; ; ; ; ; (, Journal of the American Chemical Society)
    Free, publicly-accessible full text available November 5, 2026
  2. ; ; ; ; ; ; ; (, ACS Catalysis)
    Free, publicly-accessible full text available March 7, 2026
  3. ; ; ; (, Accounts of Chemical Research)
    Full Text Available 
  4. ; ; ; (, Chemical Science)
    We report a regioselective, nickel-catalyzed syn-1,2-carbosulfenylation of non-conjugated alkenyl carbonyl compounds with alkyl/arylzinc nucleophiles and tailored N–S electrophiles. This method allows the simultaneous installation of a variety of C(sp3) and S(Ar) (or Se(Ar)) groups on to unactivated alkenes, which complements previously developed 1,2-carbosulfenylation methodology in which only C(sp2) nucleophiles are compatible. A bidentate directing auxiliary controls regioselectivity, promotes high syn-stereoselectivity with a variety of E- and Z- internal alkenes, and enables the use of a variety of electrophilic sulfenyl (and seleno) electrophiles. Among compatible electrophiles, those with N-alkyl-benzamide leaving groups were found to be especially effective, as determined through comprehensive structure–reactivity mapping. 
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